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Gold-catalyzed intermolecular coupling of sulfonylacetylene with allyl ethers: [3,3]- and [1,3]-rearrangements

Gold-catalyzed intermolecular couplings of sulfonylacetylenes with allyl ethers are reported. A cooperative polarization of alkynes both by a gold catalyst and a sulfonyl substituent resulted in an efficient intermolecular tandem carboalkoxylation. Reactions of linear allyl ethers are consistent wit...

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Bibliografske podrobnosti
Main Authors: Jun, Jungho, Yeom, Hyu-Suk, An, Jun-Hyun, Shin, Seunghoon
Format: Artigo
Jezik:Inglês
Izdano: Beilstein-Institut 2013
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3778381/
https://ncbi.nlm.nih.gov/pubmed/24062834
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.198
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