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Metal-Catalyzed Cascade Rearrangements of 3-Alkynyl Flavone Ethers

[Image: see text] Metal-mediated rearrangements of 3-alkynyl flavone ethers are reported. The overall process involves 5-endo enynecyclization to a platinum-containing spiro-oxocarbenium intermediate which may be trapped with methanol to produce spirodihydrofurans or further rearranged to afford eit...

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Detalhes bibliográficos
Main Authors: Xiong, Yuan, Schaus, Scott E., Porco, John A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3773515/
https://ncbi.nlm.nih.gov/pubmed/23574045
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol400631b
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