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Synthesis of Highly Cis, Syndiotactic ROMP Polymers Using Ruthenium Metathesis Catalysts

The first example of ruthenium-mediated ring-opening metathesis polymerization (ROMP) generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Po...

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Bibliografiske detaljer
Main Authors: Rosebrugh, Lauren E., Marx, Vanessa M., Keitz, Benjamin K., Grubbs, Robert H.
Format: Artigo
Sprog:Inglês
Udgivet: 2013
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3773019/
https://ncbi.nlm.nih.gov/pubmed/23782172
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405559y
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