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Highly Active Ruthenium Metathesis Catalysts Exhibiting Unprecedented Activity and Z-Selectivity

A novel chelated ruthenium-based metathesis catalyst bearing an N-2,6-diisopropylphenyl group is reported and displays near-perfect selectivity for the Z-olefin (>95%), as well as unparalleled TONs of up to 7400, in a variety of homodimerization and industrially relevant metathesis reactions. Thi...

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書誌詳細
主要な著者: Rosebrugh, Lauren E., Herbert, Myles B., Marx, Vanessa M., Keitz, Benjamin K., Grubbs, Robert H.
フォーマット: Artigo
言語:Inglês
出版事項: 2013
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3561903/
https://ncbi.nlm.nih.gov/pubmed/23317178
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311916m
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