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A Highly Stereoselective Addition of Lithiated Ynamides to Ellman–Davis Chiral N-tert-Butanesulfinyl Imines

[Image: see text] A highly diastereoselective addition of lithiated ynamides to Ellman–Davis chiral imines is described. While additions of N-sulfonyl ynamides are highly stereoselective even without Lewis acids, the use of BF(3)-OEt(2) completely reversed the stereoselectivity. In addition, oxazoli...

詳細記述

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書誌詳細
主要な著者: Wang, Xiao-Na, Hsung, Richard P., Qi, Rui, Fox, Sierra K., Lv, Ming-Can
フォーマット: Artigo
言語:Inglês
出版事項: 2013
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3759603/
https://ncbi.nlm.nih.gov/pubmed/23646900
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol400989x
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