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Direct Catalytic Anti-Markovnikov Addition of Carboxylic Acids to Alkenes

A direct catalytic anti-Markovnikov addition of carboxylic acids to alkenes is reported. The catalyst system is comprised of the Fukuzumi acridinium photooxidant (1) and a substoichiometric quantity of a hydrogen atom donor. Oxidizable olefins such as styrenes, trisubstituted aliphatic alkenes, and...

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Detalhes bibliográficos
Main Authors: Perkowski, Andrew J., Nicewicz, David A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3757928/
https://ncbi.nlm.nih.gov/pubmed/23808532
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4057294
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