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Kinetic Evidence of an Apparent Negative Activation Enthalpy in an Organocatalytic Process
A combined kinetic and computational study on our tryptophan-based bifunctional thiourea catalyzed asymmetric Mannich reactions reveals an apparent negative activation enthalpy. The formation of the pre-transition state complex has been unambiguously confirmed and these observations provide an exper...
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| Hlavní autoři: | , , , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Nature Publishing Group
2013
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3757351/ https://ncbi.nlm.nih.gov/pubmed/23990028 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/srep02557 |
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