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Accounting for Apparent Deviations between Calorimetric and van’t Hoff Enthalpies

BACKGROUND: In theory, binding enthalpies directly obtained from calorimetry (such as ITC) and the temperature dependence of the binding free energy (van’t Hoff method) should agree. However, previous studies have often found them to be discrepant. METHODS: Experimental binding enthalpies (both calo...

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Publicat a:Biochim Biophys Acta
Autors principals: Kantonen, Samuel A., Henriksen, Niel M., Gilson, Michael K.
Format: Artigo
Idioma:Inglês
Publicat: 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5851798/
https://ncbi.nlm.nih.gov/pubmed/29221984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbagen.2017.11.020
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