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Accounting for Apparent Deviations between Calorimetric and van’t Hoff Enthalpies

BACKGROUND: In theory, binding enthalpies directly obtained from calorimetry (such as ITC) and the temperature dependence of the binding free energy (van’t Hoff method) should agree. However, previous studies have often found them to be discrepant. METHODS: Experimental binding enthalpies (both calo...

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Détails bibliographiques
Publié dans:Biochim Biophys Acta
Auteurs principaux: Kantonen, Samuel A., Henriksen, Niel M., Gilson, Michael K.
Format: Artigo
Langue:Inglês
Publié: 2017
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5851798/
https://ncbi.nlm.nih.gov/pubmed/29221984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbagen.2017.11.020
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