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Accounting for Apparent Deviations between Calorimetric and van’t Hoff Enthalpies

BACKGROUND: In theory, binding enthalpies directly obtained from calorimetry (such as ITC) and the temperature dependence of the binding free energy (van’t Hoff method) should agree. However, previous studies have often found them to be discrepant. METHODS: Experimental binding enthalpies (both calo...

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Bibliographic Details
Published in:Biochim Biophys Acta
Main Authors: Kantonen, Samuel A., Henriksen, Niel M., Gilson, Michael K.
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5851798/
https://ncbi.nlm.nih.gov/pubmed/29221984
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bbagen.2017.11.020
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