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Chemoselective hydrosilylation of hydroxyketones
A chemoselective method for the hydrosilylation of ketones has been developed, using the combination of triphenylsilane and a catalyst prepared from Ni(COD)(2) and the simple N-heterocyclic carbene IMes. The most notable feature of this method is that free hydroxyls are largely unaffected, thus prov...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3752928/ https://ncbi.nlm.nih.gov/pubmed/23997314 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.04.055 |
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