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Stereoselective Synthesis of Conjugated Fluoro Enynes
[Image: see text] Metalation-electrophilic fluorination of TMS- and TIPS-protected 1,3-benzothiazol-2-yl (BT) propargyl sulfones gave corresponding BT fluoropropargyl sulfones, Julia-Kocienski reagents for the synthesis of fluoro enynes. Both reagents reacted with aldehydes under mild DBU, or LHMDS-...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3752389/ https://ncbi.nlm.nih.gov/pubmed/23005035 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo300971w |
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