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A Valence Bond Description of Dizwitterionic Dithiolene Character in an Oxomolybdenum-bis(dithione)
Metallo-dithiolene non-innocence is explored in an oxomolybdenum-bis(dithione) complex, [Mo(4+)O(i-Pr(2)Pipdt)(2)Cl][PF(6)] (where i-Pr(2)Pipdt is N,N’-piperazine-2,3-dithione), that possesses a piperazine ring as an integral part of the dithiolene ligand. The title complex displays unusual spectros...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3742805/ https://ncbi.nlm.nih.gov/pubmed/23956683 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ejic.201101084 |
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