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Large Ligand Folding Distortion in an Oxomolybdenum Donor-Acceptor Complex
Interligand charge transfer is examined in the novel metallo-dithiolene complex MoO(SPh)(2)((i)Pr(2)Dt(o)) (where (i)Pr(2)Dt(o) is N,N′-isopropyl-piperazine-2,3-dithione). The title complex displays a remarkable 70° “envelope” type fold of the five member dithiolene ring, which is bent upward toward...
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| Publicado no: | Inorg Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4889894/ https://ncbi.nlm.nih.gov/pubmed/26692422 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.5b02252 |
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