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n→π* Interactions of Amides and Thioamides: Implications for Protein Stability

[Image: see text] Carbonyl–carbonyl interactions between adjacent backbone amides have been implicated in the conformational stability of proteins. By combining experimental and computational approaches, we show that relevant amidic carbonyl groups associate through an n→π* donor–acceptor interactio...

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Main Authors: Newberry, Robert W., VanVeller, Brett, Guzei, Ilia A., Raines, Ronald T.
Formáid: Artigo
Teanga:Inglês
Foilsithe: American Chemical Society 2013
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3742804/
https://ncbi.nlm.nih.gov/pubmed/23663100
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja4033583
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