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Mapping Local Protein Electrostatics by EPR of pH-Sensitive Thiol-Specific Nitroxide

A first thiol-specific pH-sensitive nitroxide spin label of the imidazolidine series -methanethiosulfonic acid S-(1-oxyl-2,2,3,5,5-pentamethylimidazolidin-4-ylmethyl) ester (IMTSL) - has been synthesized and characterized. X- (9 GHz) and W-band (94 GHz) EPR spectral parameters of the new spin label...

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Autors principals: Voinov, Maxim A., Ruuge, Andres, Reznikov, Vladimir A., Grigor’ev, Igor A., Smirnov, Alex I.
Format: Artigo
Idioma:Inglês
Publicat: 2008
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3740185/
https://ncbi.nlm.nih.gov/pubmed/18426227
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi800272f
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