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Synthesis and analysis of the all-(S) side chain of phosphomycoketides: a test of NMR predictions for saturated oligoisoprenoid stereoisomers

(4S,8S,12S,16S,20S)-Pentamethylheptacosan-1-ol has been synthesized and analyzed by resolution-enhanced NMR spectroscopy with the aid of a recent set predicted spectra of all its stereoisomers. The configuration was confirmed but isomer purity of the sample (~70%) was lower than expected. A truncate...

पूर्ण विवरण

में बचाया:
ग्रंथसूची विवरण
मुख्य लेखकों: Buter, Jeffrey, Yeh, Edmund A.-H., Budavich, Owen W., Damodaran, Krishnan, Minnaard, Adriaan J., Curran, Dennis P.
स्वरूप: Artigo
भाषा:Inglês
प्रकाशित: 2013
विषय:
ऑनलाइन पहुंच:https://ncbi.nlm.nih.gov/pmc/articles/PMC3714862/
https://ncbi.nlm.nih.gov/pubmed/23582013
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo4005298
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