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Hydrogermylation of 5-Ethynyluracil Nucleosides: Formation of 5-(2-Germylvinyl)uracil and 5-(2-Germylacetyl)uracil Nucleosides
A stereoselective radical-mediated hydrogermylation of the protected 5-ethynyluracil nucleosides with trialkyl-, triaryl,- or tris(trimethylsilyl)-germanes gave (Z)-5-(2-germylvinyl)-uridine, 2'-deoxyuridine or ara-uridine as major products. Reaction of the β-triphenylgermyl vinyl radical inter...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3703441/ https://ncbi.nlm.nih.gov/pubmed/23631719 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo400590z |
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