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A facile glovebox-free strategy to significantly accelerate the syntheses of well-defined polypeptides by N-carboxyanhydride (NCA) ring opening polymerizations
A facile N(2) flow-accelerated N-carboxyanhydride ring opening polymerization (NCA ROP) is demonstrated, herein, with rigorous kinetic studies to evaluate the methodology in detail. By using n-hexylamine as initiator and γ-benzyl-L-glutamate N-carboxyanhydride (BLG-NCA) as monomer, the NCA ROP via a...
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| Main Authors: | , , , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2013
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3686519/ https://ncbi.nlm.nih.gov/pubmed/23794753 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma4007939 |
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