A facile glovebox-free strategy to significantly accelerate the syntheses of well-defined polypeptides by N-carboxyanhydride (NCA) ring opening polymerizations

A facile N(2) flow-accelerated N-carboxyanhydride ring opening polymerization (NCA ROP) is demonstrated, herein, with rigorous kinetic studies to evaluate the methodology in detail. By using n-hexylamine as initiator and γ-benzyl-L-glutamate N-carboxyanhydride (BLG-NCA) as monomer, the NCA ROP via a...

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Bibliographic Details
Main Authors: Zou, Jiong, Fan, Jingwei, He, Xun, Zhang, Shiyi, Wang, Hai, Wooley, Karen L.
Format: Artigo
Language:Inglês
Published: 2013
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3686519/
https://ncbi.nlm.nih.gov/pubmed/23794753
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ma4007939
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