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Enantioselective cyclization of enamide-ynes and application to the synthesis of the kopsifoline core
We report the palladium-catalyzed enantioselective cyclization of 1,6-enamidynes to form spirocyclic ring systems. We applied this methodology to the concise synthesis of the skeletal core of the kopsifoline alkaloids.
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| Hlavní autoři: | , , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2013
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3678774/ https://ncbi.nlm.nih.gov/pubmed/23772095 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.02.091 |
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