Mechanism Elucidation of the cis–trans Isomerization of an Azole Ruthenium–Nitrosyl Complex and Its Osmium Counterpart

[Image: see text] Synthesis and X-ray diffraction structures of cis and trans isomers of ruthenium and osmium metal complexes of general formulas (nBu(4)N)[cis-MCl(4)(NO)(Hind)], where M = Ru (1) and Os (3), and (nBu(4)N)[trans-MCl(4)(NO)(Hind)], where M = Ru (2) and Os (4) and Hind = 1H-indazole ar...

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Auteurs principaux: Gavriluta, Anatolie, Büchel, Gabriel E., Freitag, Leon, Novitchi, Ghenadie, Tommasino, Jean Bernard, Jeanneau, Erwann, Kuhn, Paul-Steffen, González, Leticia, Arion, Vladimir B., Luneau, Dominique
Format: Artigo
Langue:Inglês
Publié: American Chemical Society 2013
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3673021/
https://ncbi.nlm.nih.gov/pubmed/23675748
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic4004824
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