ロード中...
Enantioselective Synthesis of (E)-δ-Silyl-anti-Homoallylic Alcohols Via An Enantiodivergent Hydroboration-Crotylboration Reaction of a Racemic Allenylsilane
[Image: see text] The enantioselective hydroboration of racemic allenylsilane (±)-4 with ((d)Ipc)(2)BH proceeds via enantiodivergent pathways to give vinylborane 11 and crotylborane intermediate (S)-E-5. Subsequent crotylboration of aldehyde substrates with (S)-E-5 at −78 °C provides (E)-δ-silyl-ant...
保存先:
| 主要な著者: | , |
|---|---|
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2013
|
| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3663895/ https://ncbi.nlm.nih.gov/pubmed/23534391 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol4004405 |
| タグ: |
タグ追加
タグなし, このレコードへの初めてのタグを付けませんか!
|