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Bicyclic Pyrazolidinone Derivatives from Diastereoselective Catalytic [3 + 3]-Cycloaddition Reactions of Enoldiazoacetates with Azomethine Imines

[Image: see text] A highly regio- and diastereoselective synthesis of bicyclic pyrazolidinone derivatives by rhodium(II) acetate catalyzed [3+3]-annulation with enoldiazoacetates and azomethine imines has been achieved in high yield. A vinylogous reaction of the metal enol carbene with the azomethin...

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Autors principals: Qian, Yu, Zavalij, Peter J., Hu, Wenhao, Doyle, Michael P.
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3663892/
https://ncbi.nlm.nih.gov/pubmed/23477672
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol400339c
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