Main Group Multiple C–H/N–H Bond Activation of a Diamine and Isolation of A Molecular Dilithium Zincate Hydride: Experimental and DFT Evidence for Alkali Metal–Zinc Synergistic Effects

[Image: see text] The surprising transformation of the saturated diamine (iPr)NHCH(2)CH(2)NH(iPr) to the unsaturated diazaethene [(iPr)NCH=CHN(iPr)](2-) via the synergic mixture nBuM, (tBu)(2)Zn and TMEDA (where M = Li, Na; TMEDA = N,N,N′,N′-tetramethylethylenediamine) has been investigated by multi...

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Detalhes bibliográficos
Main Authors: Campbell, Ross, Cannon, Daniel, García-Álvarez, Pablo, Kennedy, Alan R., Mulvey, Robert E., Robertson, Stuart D., Saßmannshausen, Jörg, Tuttle, Tell
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2011
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3662402/
https://ncbi.nlm.nih.gov/pubmed/21777000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205547h
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