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Aestuaramides, a natural library of cyanobactin cyclic peptides resulting from isoprene-derived Claisen rearrangements

We report 12 cyanobactin cyclic peptides, the aestuaramides, from the cultivated cyanobacterium Lyngbya aestuarii. We show that aestuaramides are synthesized enzymatically as reverse O-prenylated tyrosine ethers that subsequently undergo a Claisen rearrangement to produce forward C-prenylated tyrosi...

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Autors principals: McIntosh, John A., Lin, Zhenjian, Tianero, Ma. Diarey, Schmidt, Eric W.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3657307/
https://ncbi.nlm.nih.gov/pubmed/23411099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/cb300614c
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