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Synthesis of Z-(Pinacolato)allylboron and Z-(Pinacolato)alkenylboron Compounds through Stereoselective Catalytic Cross-Metathesis

The first examples of catalytic cross-metathesis (CM) reactions that furnish Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds are disclosed. Products are generated with high Z selectivity by the use of a W-based mono-aryloxide pyrrolide (MAP) complex (up to 91% yield and >98:2 Z:...

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Hlavní autoři: Kiesewetter, Elizabeth T., O'Brien, Robert V., Meek, Simon J., Yu, Elsie C., Schrock, Richard R., Hoveyda, Amir H.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2013
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3649762/
https://ncbi.nlm.nih.gov/pubmed/23586708
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja403188t
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