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Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes

We have prepared the first examples of B9-connected trivalent aryl and alkyl phosphinoborane species via Pd-catalyzed phosphination of 9-iodo-meta-carborane. Our studies highlight the unique electronic features of the B9-connected meta-carboranyl moiety as compared to its C1-based analogue. This wor...

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Bibliografske podrobnosti
Main Authors: Spokoyny, Alexander M., Lewis, Calvin D., Teverovskiy, Georgiy, Buchwald, Stephen L.
Format: Artigo
Jezik:Inglês
Izdano: 2012
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3647701/
https://ncbi.nlm.nih.gov/pubmed/23667288
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om301116x
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