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Substituent Effects on the Reactivity of Benzoquinone Derivatives with Thiols

Benzoquinone (BQ) is an extremely potent electrophilic contact allergen that haptenates endogenous proteins through Michael addition (MA). It is also hypothesized that BQ may haptenate proteins via free radical formation. The objective of this study was to assess the inductive effects (activating an...

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Detalhes bibliográficos
Main Authors: Mbiya, Wilbes, Chipinda, Itai, Siegel, Paul D., Mhike, Morgen, Simoyi, Reuben H.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3644549/
https://ncbi.nlm.nih.gov/pubmed/23237669
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/tx300417z
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