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Intramolecular Oxyallyl–Carbonyl (3+2) Cycloadditions

Cycloadditions involving oxyallyl intermediates typically require an electron-rich diene or alkene, but we have discovered the first examples of the cycloaddition of heteroatom-stabilized oxyallyls onto carbonyl groups. An oxazolidinone-substituted oxyallyl undergoes chemoselective (3+2) cycloadditi...

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Autors principals: Krenske, Elizabeth H., He, Shuzhong, Huang, Jian, Du, Yunfei, Houk, K. N., Hsung, Richard P.
Format: Artigo
Idioma:Inglês
Publicat: 2013
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3642281/
https://ncbi.nlm.nih.gov/pubmed/23544997
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja312459b
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