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Complete σ* intramolecular aromatic hydroxylation mechanism through O(2) activation by a Schiff base macrocyclic dicopper(I) complex
In this work we analyze the whole molecular mechanism for intramolecular aromatic hydroxylation through O(2) activation by a Schiff hexaazamacrocyclic dicopper(I) complex, [Cu(I)(2)(bsH2m)](2+). Assisted by DFT calculations, we unravel the reaction pathway for the overall intramolecular aromatic hyd...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3628990/ https://ncbi.nlm.nih.gov/pubmed/23616799 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.63 |
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