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Complete σ* intramolecular aromatic hydroxylation mechanism through O(2) activation by a Schiff base macrocyclic dicopper(I) complex

In this work we analyze the whole molecular mechanism for intramolecular aromatic hydroxylation through O(2) activation by a Schiff hexaazamacrocyclic dicopper(I) complex, [Cu(I)(2)(bsH2m)](2+). Assisted by DFT calculations, we unravel the reaction pathway for the overall intramolecular aromatic hyd...

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Bibliographic Details
Main Authors: Poater, Albert, Solà, Miquel
Format: Artigo
Language:Inglês
Published: Beilstein-Institut 2013
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3628990/
https://ncbi.nlm.nih.gov/pubmed/23616799
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.63
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