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Carbolithiation of N-alkenyl ureas and N-alkenyl carbamates
N-Alkenyl ureas and N-alkenyl carbamates, like other N-acyl enamines, are typically nucleophilic at their β-carbon. However, by incorporating an α-aryl substituent, we show that they will also undergo attack at the β-carbon by organolithium nucleophiles, leading to the products of carbolithiation. T...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
Beilstein-Institut
2013
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3628850/ https://ncbi.nlm.nih.gov/pubmed/23616806 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.9.70 |
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