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STILLE CROSS-COUPLING REACTIONS OF ARYL MESYLATES AND TOSYLATES USING A BIARYLPHOSPHINE BASED CATALYST SYSTEM()

A catalyst system for the Stille cross-coupling reactions of aryl mesylates and tosylates is reported. Using the combination of Pd(OAc)(2), XPhos, and CsF in t-BuOH an array of aryl and heteroaryl sulfonates were successfully employed in these reactions. Morever, heteroarylstannanes, such as furyl,...

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Bibliografiske detaljer
Main Authors: Naber, John R., Fors, Brett P., Wu, Xiaoxing, Gunn, Jonathon, Buchwald, Stephen L.
Format: Artigo
Sprog:Inglês
Udgivet: 2009
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3626283/
https://ncbi.nlm.nih.gov/pubmed/23596345
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3987/COM-09-S(S)105
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