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Cafestol to Tricalysiolide B and Oxidized Analogues: Biosynthetic and Derivatization Studies Using Non-heme Iron Catalyst Fe(PDP)

The tricalysiolides are a recently isolated class of diterpene natural products featuring the carbon backbone of the well-known coffee extract, cafestol. Herein we validate the use of our non-heme iron complex, Fe(PDP), as an oxidative tailoring enzyme mimic to test the proposal that this class of n...

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Detalhes bibliográficos
Main Authors: Bigi, Marinus A., Liu, Peng, Zou, Lufeng, Houk, K. N., White, M. Christina
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3622267/
https://ncbi.nlm.nih.gov/pubmed/23585710
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-0032-1317708
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