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Copper-Mediated Fluorination of Arylboronate Esters. Identification of a Copper(III) Fluoride Complex

A method for the direct conversion of arylboronate esters to aryl fluorides under mild conditions with readily available reagents is reported. Tandem reactions have also been developed for the fluorination of arenes and aryl bromides through aryl-boronate ester intermediates. Mechanistic studies sug...

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Main Authors: Fier, Patrick S., Luo, Jingwei, Hartwig, John F.
Formato: Artigo
Idioma:Inglês
Publicado: 2013
Assuntos:
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3619937/
https://ncbi.nlm.nih.gov/pubmed/23384209
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja310909q
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