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Photoinitiated release of an aziridinium ion precursor for the temporally-controlled alkylation of nucleophiles

A photo-activatable aziridinium precursor has been developed to investigate the possibility of a photo-initiated traditional nucleophilic reaction. The photolysis of a quaternary amine yields a tertiary amine and has allowed us to temporally-control aziridinium formation and subsequent alkylation of...

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Detalhes bibliográficos
Main Authors: McCarron, Stephen T., Feliciano, Mariel, Johnson, Jeffreys N., Chambers, James J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3609034/
https://ncbi.nlm.nih.gov/pubmed/23489632
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bmcl.2013.02.044
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