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Lewis acid catalysis of phosphoryl transfer from a copper(II)-NTP complex in a kinase ribozyme
The chemical strategies used by ribozymes to enhance reaction rates are revealed in part from their metal ion and pH requirements. We find that kinase ribozyme K28(1-77)C, in contrast with previously characterized kinase ribozymes, requires Cu(2+) for optimal catalysis of thiophosphoryl transfer fro...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Oxford University Press
2013
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3597699/ https://ncbi.nlm.nih.gov/pubmed/23358821 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1093/nar/gkt039 |
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