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Long Range Proton-Coupled Electron Transfer Reactions of Bis(imidazole) Iron Tetraphenylporphyrins Linked to Benzoates
Concerted proton-electron transfer (CPET) reactions in iron carboxy-tetraphenylporphyrin complexes have been investigated using both experimental and theoretical methods. Synthetic heme models abstract H(+) and e(−) from the hydroxylamine TEMPOH or an ascorbate derivative, and the kinetics of the TE...
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| Hauptverfasser: | , , , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2013
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3593309/ https://ncbi.nlm.nih.gov/pubmed/23493584 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz400029w |
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