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Long Range Proton-Coupled Electron Transfer Reactions of Bis(imidazole) Iron Tetraphenylporphyrins Linked to Benzoates

Concerted proton-electron transfer (CPET) reactions in iron carboxy-tetraphenylporphyrin complexes have been investigated using both experimental and theoretical methods. Synthetic heme models abstract H(+) and e(−) from the hydroxylamine TEMPOH or an ascorbate derivative, and the kinetics of the TE...

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Bibliografski detalji
Glavni autori: Warren, Jeffrey J., Menzeleev, Artur R., Kretchmer, Joshua S., Miller, Thomas F., Gray, Harry B., Mayer, James M.
Format: Artigo
Jezik:Inglês
Izdano: 2013
Teme:
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3593309/
https://ncbi.nlm.nih.gov/pubmed/23493584
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jz400029w
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