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Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes

[Image: see text] This paper describes the catalytic asymmetric diamination of alkyl dienes using N,N’-di-tert-butylthiadiaziridine 1,1-dioxide in the presence of Pd(0) and a chiral phosphoramidite ligand to give cyclic sulfamides in high yield and high ee. The diamination is also amenable to gram s...

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Detalhes bibliográficos
Main Authors: Cornwall, Richard G., Zhao, Baoguo, Shi, Yian
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3587789/
https://ncbi.nlm.nih.gov/pubmed/23362985
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol303469a
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