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Stereochemically Probing the photo-Favorskii Rearrangement: A Mechanistic Investigation
Using model (R)-2-acetyl-2-phenyl acetate esters of (S)- or (R)-α-substituted-p-hydroxybutyrophenones (S,R)-12a and (R,R)-12b, we have shown that a highly efficient photo-Favorskii rearrangement proceeds through a series of intermediates to form racemic rearrangement products. The stereogenic methin...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2012
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3586294/ https://ncbi.nlm.nih.gov/pubmed/23057737 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo301640q |
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