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Pd(II)-Catalyzed Enantioselective C–H Activation/C–O Bond Formation: Synthesis of Chiral Benzofuranones

Pd(II)-catalyzed enantioselective C–H activation of phenylacetic acids followed by an intramolecular C–O bond formation afforded chiral benzofuranones. This reaction provides the first example of enantioselecctive C–H functionalizations through Pd(II)/Pd(IV) redox catalysis.

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Detalhes bibliográficos
Main Authors: Cheng, Xiu-Fen, Li, Yan, Su, Yi-Ming, Yin, Feng, Wang, Jian-Yong, Sheng, Jie, Vora, Harit U., Wang, Xi-Sheng, Yu, Jin-Quan
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3578945/
https://ncbi.nlm.nih.gov/pubmed/23305171
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja311259x
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