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A Bidirectional S(E)' Strategy for 1,5-syn and 1,5-anti Stereocontrol Toward the Synthesis of Complex Polyols

[Image: see text] Studies report a bidirectional S(E)' strategy applicable for the stereocontrolled synthesis of nonracemic 1,5-syn and 1,5-anti diols and their derivatives. Nonracemic 1,3,2-diazaborolidine auxiliaries are incorporated by chemoselective tin—boron exchange to provide reactive al...

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Detalhes bibliográficos
Main Authors: Williams, David R., Claeboe, Christopher D., Liang, Bo, Zorn, Nicolas, Chow, Nicholas S. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3565749/
https://ncbi.nlm.nih.gov/pubmed/22813207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3015682
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