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Di-peptide Based Models of Nickel Superoxide Dismutase: Solvent Effects Highlight a Critical Role to Ni-S Bonding and Active Site Stabilization

Nickel superoxide dismutase (Ni-SOD) catalyzes the disproportionation of the superoxide radical to O(2) and H(2)O(2) utilizing the Ni(III/II) redox couple. The Ni center in Ni-SOD resides in an unusual coordination environment that is distinct from other SODs. In the reduced state (Ni-SOD(red)), the...

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Hlavní autoři: Gale, Eric M., Cowart, Darin M., Scott, Robert A., Harrop, Todd C.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3561719/
https://ncbi.nlm.nih.gov/pubmed/21932766
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic2016462
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