Using Nazarov Electrocyclization to Stage Chemoselective [1,2]-Migrations: Stereoselective Synthesis of Functionalized Cyclopentenones

Highly functionalized cyclopentenones are prepared stereospecifically based on a chemoselective copper(II)-mediated Nazarov/Wagner-Meerwein rearrangement sequence. After the initial 4π electrocyclization, this reaction involves two sequential [1,2]-migrations depending upon both migratory ability an...

Descrición completa

Gardado en:
Detalles Bibliográficos
Main Authors: Lebœuf, David, Huang, Jie, Gandon, Vincent, Frontier, Alison J.
Formato: Artigo
Idioma:Inglês
Publicado: 2011
Assuntos:
Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3560917/
https://ncbi.nlm.nih.gov/pubmed/21953873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201104870
Tags: Engadir etiqueta
Sen Etiquetas, Sexa o primeiro en etiquetar este rexistro!

Títulos similares