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Catalytic Enantioselective Cyclization and C3-Fluorination of Polyenes
(xylyl-phanephos)Pt(2+) in combination with XeF(2) mediates the consecutive diastereoselective cation-olefin cyclization/fluorination of polyene substrates. Isolated yields were typically in the 60s while enantioselectivies reached as high as 87%. The data are consistent with a stereoretentive fluor...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2013
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3552331/ https://ncbi.nlm.nih.gov/pubmed/23282101 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3116795 |
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