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A Three-Stage Mechanistic Model for Ammonia Borane Dehydrogenation by Shvo’s Catalyst
We propose a mechanistic model for three-stage dehydrogenation of ammonia borane (AB) catalyzed by Shvo’s cyclopentadienone-ligated ruthenium complex. We provide evidence for a plausible mechanism for catalyst deactivation, the transition from fast catalysis to slow catalysis, and relate those findi...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2012
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3546831/ https://ncbi.nlm.nih.gov/pubmed/23335832 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om300562d |
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