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α-Amination of keto-nitrones via Multihetero-Cope rearrangement employing an imidoyl chloride reagent
α-Aminations of ketone-derived nitrones have been developed via [3,3]-rearrangement of the intermediates generated upon condensation with imidoyl chlorides. Careful reagent selection provides synthetically attractive amino protecting groups. The enediamide or α′-carbamoyl enamide products can be hyd...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2012
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3545407/ https://ncbi.nlm.nih.gov/pubmed/22733086 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c2cc33401a |
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