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Synthesis of Chamaecypanone C Analogues from in situ-Generated Cyclopentadienones and their Biological Evaluation

A rhodium-catalyzed dehydrogenation protocol has been developed for conversion of 3,5-diarylcyclopentenones to the corresponding 2,4-diarylcyclopentadienones. Using this protocol, analogues of the cytotoxic agent chamaecypanone C have been synthesized via Diels-Alder cycloaddition between the cyclop...

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Detalhes bibliográficos
Main Authors: Dong, Suwei, Qin, Tian, Hamel, Ernest, Beutler, John A., Porco, John A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3542833/
https://ncbi.nlm.nih.gov/pubmed/23110297
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3084708
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