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Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides

The copper(I) thiophenolato complexes 1–3 containing 1,10-phenanthroline (phen) and 2,9-dimethyl-1,10-phenanthroline (Me(2)phen) were isolated in excellent yields from reactions of [CuOtBu](4) with the dative ligands and subsequent addition of 1 equiv of arylthiol and characterized spectroscopically...

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Autors principals: Chen, Chaohuang, Weng, Zhiqiang, Hartwig, John F.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3540417/
https://ncbi.nlm.nih.gov/pubmed/23316098
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om300711c
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