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New phosphine-diamine and phosphine-amino-alcohol tridentate ligands for ruthenium catalysed enantioselective hydrogenation of ketones and a concise lactone synthesis enabled by asymmetric reduction of cyano-ketones
Enantioselective hydrogenation of ketones is a key reaction in organic chemistry. In the past, we have attempted to deal with some unsolved challenges in this arena by introducing chiral tridentate phosphine-diamine/Ru catalysts. New catalysts and new applications are presented here, including the s...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
BioMed Central
2012
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| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3538564/ https://ncbi.nlm.nih.gov/pubmed/23216944 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1186/1752-153X-6-151 |
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